Search results for "31P NMR spectroscopy"

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Lattice Opening upon Bulk Reductive Covalent Functionalization of Black Phosphorus

2019

The chemical bulk reductive covalent functionalization of thin-layer black phosphorus (BP) using BP intercalation compounds has been developed. Through effective reductive activation, covalent functionalization of the charged BP by reaction with organic alkyl halides is achieved. Functionalization was extensively demonstrated by means of several spectroscopic techniques and DFT calculations; the products showed higher functionalization degrees than those obtained by neutral routes.

Materials scienceIntercalation (chemistry)reductive routeFOS: Physical sciencesHalideApplied Physics (physics.app-ph)010402 general chemistryblack phosphorus01 natural sciences7. Clean energyCatalysisBlack phosphorusCovalent functionalizationsymbols.namesakeLattice (order)MaterialsAlkylchemistry.chemical_classification010405 organic chemistryCommunicationQuímicaPhysics - Applied PhysicsGeneral ChemistryCommunicationsEspectroscòpia Raman0104 chemical sciencesCrystallographycovalent functionalizationchemistryBlack Phosphorusddc:540Raman spectroscopysymbolsSurface modification31P NMR spectroscopyRaman spectroscopy

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